A colorimetric approach towards polycyclic aromatic hydrocarbon sensing

Journal Publication ResearchOnline@JCU
Woodland, Walmiria;Motti, Cherie A.;Irving, Paul;Van Herwerden, Lynne;Vamvounis, George
Abstract

The colorimetric detection of polycyclic aromatic hydrocarbons (PAHs) was achieved using photochromic compounds. This technique exploits the ability of the photochromic compound to reversibly change from a colourless to a coloured compound using ultraviolet light and visible light. In the presence of a PAH, this photoisomerization is inhibited. The degree of inhibition corresponded to the molar absorptivity and excitation wavelength of the PAH, and with a limit of detection in the micromolar range, the current method delivers a highly sensitive and selective technology. In addition, PAH mixtures were successfully identified using this method, providing a potentially fast in-field sensing technology for the identification of likely sources of spilled oil.

Journal

Australian Journal of Chemistry

Publication Name

Australian Journal of Chemistry

Volume

69

ISBN/ISSN

1445-0038

Edition

N/A

Issue

11

Pages Count

4

Location

N/A

Publisher

CSIRO Publishing

Publisher Url

N/A

Publisher Location

N/A

Publish Date

N/A

Url

N/A

Date

N/A

EISSN

N/A

DOI

10.1071/CH16176