Lanthanoid pseudo-Grignard reagents: A review

Journal Publication ResearchOnline@JCU
Halim, Md Abdul;Guo, Zhifang;Blair, Victoria L.;Deacon, Glen B.;Junk, Peter C.
Zhifang GuoPeter Junk
Abstract

This review covers the progress of the chemistry of divalent lanthanoid pseudo-Grignard, compounds, with E-Ln-X bonding (E = C, N, O; X = I, Br, Cl, F), especially since the 2002 review of Petrov et al. (2002)[1]. Emphasis is on synthetic pathways and the structures of these compounds. Their use in oxidation and metathesis reactions is discussed together with a consideration of interactions with organic substrates. The compounds appear to have considerable untapped potential.

Journal

Journal of Organometallic Chemistry

Publication Name

Journal of Organometallic Chemistry

Volume

1010

ISBN/ISSN

1872-8561

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Pages Count

13

Location

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Publisher

Elsevier

Publisher Url

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Publisher Location

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Publish Date

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Url

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Date

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EISSN

N/A

DOI

10.1016/j.jorganchem.2024.123094