Formation of folded complexes retaining intramolecular H-bonding in the extraction of nickel(II) by phenolic oxime and aliphatic diamine ligands

Journal Publication ResearchOnline@JCU
Hultgren, Victoria M.;Atkinson, Ian M.;Beddoes, Roy L.;Collinson, David;Garner, C. David;Helliwell, Maeleine;Lindoy, Leonard F.;Tasker, Peter A.
Ian Atkinson
Abstract

Solvent extraction of Ni^II by phenolic oximes is enhanced significantly by addition of aliphatic diamines; octahedral [Ni(II)(phenolate-oxime)₂(diamine)] complexes have been characterised that contain a novel folded conformation, retaining intramolecular hydrogen bonding between the two oxime ligands.

Journal

Chemical Communications

Publication Name

Chemical Communications

Volume

6

ISBN/ISSN

1364-548X

Edition

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Issue

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Pages Count

2

Location

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Publisher

Royal Society of Chemistry

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Url

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Date

N/A

EISSN

N/A

DOI

10.1039/b009267n