Challenging targets in rare earth metalorganic chemistry (Old ID 24847)

Principal Investigator

This project aims to prepare technically demanding, highly reactive rare earth organometallic and metal-organic compounds, especially from the free metals, and to determine their structures and reactivity. The challenging target systems include coordination stabilised novel ligands, pseudo-Grignard reagents LnR(X) including the rare fluorides, complexes primed for C-F activation, and intermediates from use of lanthanoid reagents in organic synthesis. The studies provide a knowledge base and expertise for the utilisation of Australia's abundant rare earths in chemical manufacture, catalysis, and recycling, and will transform the current behaviour of the elements.

17 May 2019 - 31 Dec 2022

N/A