When is a reported air-stable PrIV complex not a PrIV complex? Answer: when it is PrIII

Journal Publication ResearchOnline@JCU
Guo, Zhifang;Deacon, Glen B.;Junk, Peter C.
Peter JunkZhifang Guo
Abstract

All the data recently reported for the purported air/water stable PrIV complex, [(L)PrIV(L)4(OH0.94Cl0.06)2PrIV(L)]n (L = N-acetylanthranilate) [1], have been reinterpreted to show that it is, in fact, the PrIII complex [Pr2L6(H2O)2]n. Importantly, it is isomorphous with its reported EuIII analogue [Eu2L6(H2O)2]n [2], providing further evidence of the incorrect assignment in the literature.

Journal

Journal of Coordination Chemistry

Publication Name

Journal of Coordination Chemistry

Volume

78

ISBN/ISSN

1029-0389

Edition

N/A

Issue

1-3

Pages Count

6

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Publisher

Taylor & Francis

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Date

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EISSN

N/A

DOI

10.1080/00958972.2024.2384711