A magmatic copper and fluid source for the sediment-hosted Mount Isa deposit

Journal Publication ResearchOnline@JCU
Sanislav, I.V.;Mathur, R.;Rea, P.;Dirks, P.H.G.M.;Mahan, B.;Godfrey, L.;Degeling, H.
Abstract

The world class Mount Isa deposit is a unique, sediment-hosted, copper deposit with no known equivalent around the world and a controversial origin. We report δ65Cu values (n = 90) from chalcopyrite grains collected systematically across the entire deposit. The δ65Cu shows a unimodal distribution with limited variability (min = −0.87 ‰; max = 0.88 ‰) and an average value (+0.13 ‰) comparable to average igneous rocks. In general, the δ65Cu values in chalcopyrite are lower near major structures and heavier further away, consistent with equilibrium fractionation with distance from the fluid source. The range in δ65Cu of chalcopyrite from the Mount Isa deposit is less variable compared to sedimentary copper, VMS and porphyry/epithermal deposits, but similar to Michigan deposits; meanwhile, average δ65Cu at Mt. Isa is distinctly higher than sedimentary copper deposits, but similar to VMS, porphyry/epithermal and Michigan deposits. These data suggest that, from a copper isotope perspective, the Mount Isa deposit is clearly different from sedimentary copper deposits and more like VMS, porphyry copper/epithermal and Michigan style deposits. The average δ65Cu (+0.13 ‰) is almost identical to the average δ65Cu (+0.14 ‰) from Proterozoic basalts and suggests that copper was sourced from the underlying mafic rocks; the limited fractionation and the normal distribution of the δ65Cu indicate a very effective leaching mechanism and transport by a hot fluid from which chalcopyrite precipitated without significant fractionation of copper isotopes.

Journal

Geochemical Perspectives Letters

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27

ISBN/ISSN

2410-3403

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Pages Count

6

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European Association of Geochemistry

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DOI

10.7185/geochemlet.2330