Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes
Journal Publication ResearchOnline@JCUShephard, Angus C.G.;Daniels, Daisy P.;Deacon, Glen B.;Guo, Zhifang;Jaroschik, Florian;Junk, Peter C.
Abstract
The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C–P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.
Journal
Chemical Communications
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Volume
58
ISBN/ISSN
1364-548X
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Pages Count
4
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Publisher
Royal Society of Chemistry
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EISSN
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DOI
10.1039/d2cc00698g