Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates
Journal Publication ResearchOnline@JCUWerner, Daniel;Bayer, Uwe;Rad, Nazli E.;Junk, Peter C.;Deacon, Glen B.;Anwander, Reiner
Abstract
Homoleptic [La(Me(2)pz)(3)](n) (Me(2)pz = 3,5-dimethylpyrazolato) is a mu-eta(2):eta(5)-Me(2)pz coordination polymer with 12-coordinate La atoms in an unusual eta(5):eta(5) Me(2)pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce-4(Me(2)pz)(12)] featuring six different Me(2)pz coordination modes.
Journal
Dalton Transactions
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Volume
47
ISBN/ISSN
1477-9234
Edition
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Issue
17
Pages Count
4
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Publisher
Royal Society of Chemistry
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EISSN
N/A
DOI
10.1039/c8dt00338f