RF plasma polymerization of orange oil and characterization of the polymer thin films

Journal Publication ResearchOnline@JCU
Alancherry, Surjith;Bazaka, Kateryna;Jacob, Mohan V.
Abstract

The present study describes an environmentally friendly approach to fabricate hydrocarbon-rich polymer thin films from a bio-renewable precursor, orange oil, cold extracted from orange peels using radio frequency plasma polymerization. The polymer thin films fabricated at different RF power level (10–75 W) were characterized with variable angle spectroscopic ellipsometry, UV–visible spectroscopy, Fourier transform infrared spectroscopy and atomic force microscopy. Optical characterization showed that independent of deposition power films exhibited good transparency (~ 90%) in the visible region and a refractive index of 1.55 at 500 nm. The optical band gap measured around 3.60 eV and falls within the insulating region. The atomic force microscopic images revealed that the surface is pinhole-free in nature and smooth at nanoscale, with average surface roughness dependent on the deposition power. Film hardness increased from 0.50 to 0.78 GPa as applied power increased from 10 to 75 W.

Journal

Journal of Polymers and the Environment

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Volume

26

ISBN/ISSN

1572-8919

Edition

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Issue

7

Pages Count

9

Location

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Publisher

Springer

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Publisher Location

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Publish Date

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Date

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EISSN

N/A

DOI

10.1007/s10924-018-1178-7