Electroanalytical ventures at nanoscale interfaces between immiscible liquids
Journal Publication ResearchOnline@JCUAbstract
Ion transfer at the interface between immiscible electrolyte solutions offers many benefits to analytical chemistry, including the ability to detect nonredox active ionized analytes, to detect ions whose redox electrochemistry is accompanied by complications, and to separate ions based on electrocontrolled partition. Nanoscale miniaturization of such interfaces brings the benefits of enhanced mass transport, which in turn leads to improved analytical performance in areas such as sensitivity and limits of detection. This review discusses the development of such nanoscale interfaces between immiscible liquids and examines the analytical advances that have been made to date, including prospects for trace detection of ion concentrations.
Journal
Annual Review of Analytical Chemistry
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Volume
9
ISBN/ISSN
1936-1335
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Pages Count
17
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Publisher
Annual Reviews
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Date
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EISSN
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DOI
10.1146/annurev-anchem-071015-041415