Rare-earth N,N'-diaryformamidinate complexes

Journal Publication ResearchOnline@JCU
Deacon, Glen B.;Hossain, Md Elius;Junk, Peter C.;Salehisaki, Mehdi
Abstract

This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N,N'-bis(aryl)forma midinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed.

Journal

Coordination Chemistry Reviews

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340

ISBN/ISSN

1873-3840

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Publisher

Elsevier

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DOI

10.1016/j.ccr.2017.02.011