Synthesis and characterisation of heterobimetallic lanthanoid o-based cluster/cages
Journal Publication ResearchOnline@JCUAndrews, Philip C.;Bousrez, Guillaume;Junk, Peter C.;Thielemann, Dominique T.;Werrett, Melissa V.
Abstract
The synthesis of new mono-and bimetallic lanthanoid cluster compounds is reported. The metal-to metal ratios of tetra-and pentanuclear clusters were determined by energy-dispersive X-ray spectroscopy (EDS). The EDS results show that, for an equal proportion of lanthanide salts introduced, different metal-to-metal ratios are achieved in the clusters. This ratio appears to be dependent on the size and electron density of the metal atoms. Studies realized the best conditions to achieve a 1:1 ratio.
Journal
European Journal of Inorganic Chemistry
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Volume
2017
ISBN/ISSN
1099-0682
Edition
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Issue
3
Pages Count
6
Location
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Publisher
Wiley
Publisher Url
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Publisher Location
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Publish Date
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Url
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Date
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EISSN
N/A
DOI
10.1002/ejic.201601264