Expectation values of single-particle operators in the random phase approximation ground state

Journal Publication ResearchOnline@JCU
Kosov, D.S.
Abstract

We developed a method for computing matrix elements of single-particle operators in the correlated random phase approximation ground state. Working with the explicit random phase approximation ground state wavefunction, we derived a practically useful and simple expression for a molecular property in terms of random phase approximation amplitudes. The theory is illustrated by the calcula- tion of molecular dipole moments for a set of representative molecules.

Journal

Journal of Chemical Physics

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Volume

146

ISBN/ISSN

1089-7690

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Pages Count

4

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Publisher

American Institute of Physics

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DOI

10.1063/1.4974985