Lanthanoid induced C–F activation of all fluorine atoms of one CF3 group

Journal Publication ResearchOnline@JCU
Deacon, Glen B.;Junk, Peter C.;Werner, Daniel
Peter Junk
Abstract

The lanthanum formamidinate complex [La(CF3Form)3] {CF3FormH = N,N'-bis(2-trifluoromethylphenyl)formamidine}, which has six La–F interactions in the solid-state structure, readily undergoes C–F activation of all fluorine atoms of one CF3 group to give LaF3, and two isomeric polytrifluoromethylphenyl-substituted polyamidines, one containing a 1,2,3,4-tetrahydroquinazoline heterocyclic core.

Journal

European Journal of Inorganic Chemistry

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Volume

2015

ISBN/ISSN

1099-0682

Edition

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Issue

9

Pages Count

6

Location

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Publisher

Wiley

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Publisher Location

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Publish Date

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Date

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EISSN

N/A

DOI

10.1002/ejic.201500137