Aluminum and indium complexes derived from guanidines, triazenes, and amidines

Journal Publication ResearchOnline@JCU
Cole, Marcus L.;Davies, Aaron J.;Jones, Cameron;Junk, Peter C.;McKay, Alasdair I.;Stasch, Andreas
Abstract

The reaction of guanidines, triazenes, amidines, and lithium amidinates with trimethylamine alane ([AlH3(NMe3)]), lithium tetrahydridoaluminate, trimethylaluminum, aluminum trichloride, and indium trichloride is reported. Equimolar reactions utilising hindered N,N'-bis(2, 6-diisopropylphenyl)guanidines afford [{AlX2L}n] species through hydrogen elimination (X = H) from [AlH3(NMe3)] (n = 2) with HCGiso (1), HDGiso (2), or HDPiso (3) [CGiso = N,N'-bis(2, 6-disopropylphenyl)-N"-dicyclohexylguanidinate, DGiso = N,N',N"-tris(2, 6-diisopropylphenyl)guanidinate, DPiso = N,N'-bis(2, 6-diisopropylphenyl)-P-2, 6-diisopropylphenylphosphguanidinate], or through methane elimination (X = Me) from AlMe3 [n = 1, L = CGiso (5)]. The analogous reactions of the triazene HTiso with LiAlH4 and AlMe3 selectively afford [AlH(Tiso)2] (4) and [AlMe2(Tiso)] (6), respectively [Tiso = 1, 3-bis(2, 6-diisopropylphenyl)triazenide]. Reactions of N,N'-bis(aryl)formamidines/ates with half an equivalent of AlMe3/AlCl3 result in [AlXL2] complexes [X = Me; L = Fxy (7) or Fet (8); X = Cl; L = Fet (9) or L = Fiso (10)] [Fxy = N,N'-bis(2, 6-dimethylphenyl)formamidinate, Fet = N,N'-bis(2, 6-diethylphenyl)formamidinate, Fiso = N,N'-bis(2, 6-diisopropylphenyl)formamidinate]. Treatment of 1 with one equivalent of I2 yields [AlI2(CGiso)] (11). Attempts to prepare [InCl2L] congeners of 11 with L = Fxy and Fet led to the isolation of prodigious quantities of [InCl3(HFxy)2] (12) and [InCl2(Fet)(HFet)] (13) due to adventitious water. The X-ray crystal structures of 1–13 are reported.

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641

ISBN/ISSN

1521-3749

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Issue

12-13

Pages Count

12

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Publisher

Wiley

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DOI

10.1002/zaac.201500556