The role of electron-impact vibrational excitation in electron transport through gaseous tetrahydrofuran
Journal Publication ResearchOnline@JCUAbstract
In this paper, we report newly derived integral cross sections (ICSs) for electron impact vibrational excitation of tetrahydrofuran (THF) at intermediate impact energies. These cross sections extend the currently available data from 20 to 50 eV. Further, they indicate that the previously recommended THF ICS set [Garland et al., Phys. Rev. A 88, 062712 (2013)] underestimated the strength of the electron-impact vibrational excitation processes. Thus, that recommended vibrational cross section set is revised to address those deficiencies. Electron swarm transport properties were calculated with the amended vibrational cross section set, to quantify the role of electron-driven vibrational excitation in describing the macroscopic swarm phenomena. Here, significant differences of up to 17% in the transport coefficients were observed between the calculations performed using the original and revised cross section sets for vibrational excitation.
Journal
Journal of Chemical Physics
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Volume
142
ISBN/ISSN
1089-7690
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Pages Count
7
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Publisher
American Institute of Physics
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DOI
10.1063/1.4915889