Structural characterization of γ-terpinene thin films using mass spectroscopy and X-Ray photoelectron spectroscopy

Journal Publication ResearchOnline@JCU
Ahmad, Jakaria;Bazaka, Kateryna;Whittle, Jason D.;Michelmore, Andrew;Jacob, Mohan V.
Abstract

Understanding the polymerization mechanism of a precursor is indispensable to enhance the requisite material properties. In situ mass spectroscopy and X-ray photoelectron spectroscopy is used in this study to understand the RF plasma polymerization of γ-terpinene. High-resolution mass spectra positive ion mass spectrometry data of the plasma phase demonstrates the presence of oligomeric species of the type [M+H]+ and [2M+H]+, where M represents a unit of the starting material. In addition, there is abundant fragmented species, with most dominant being [M+] (136 m/z), C10H13+ (133 m/z), C9H11+ (119 m/z), and C7H9+ (93 m/z). The results reported in this manuscript enables to comprehend the relationship between the degree of incorporation of oxygen and the rate of deposition with the input RF power.

Journal

Plasma Processes and Polymers

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Volume

12

ISBN/ISSN

1612-8869

Edition

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Issue

10

Pages Count

10

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Publisher

Wiley

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Publisher Location

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Publish Date

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Url

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Date

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EISSN

N/A

DOI

10.1002/ppap.201400220