A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene
Journal Publication ResearchOnline@JCUDeacon, G.B.;Jaroschik, F.;Junk, P.C.;Kelly, R.P.
Abstract
The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.
Journal
Chemical Communications
Publication Name
Chemical Communications
Volume
50
ISBN/ISSN
1364-548X
Edition
N/A
Issue
73
Pages Count
3
Location
N/A
Publisher
Royal Society of Chemistry
Publisher Url
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Publisher Location
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Publish Date
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Url
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Date
N/A
EISSN
N/A
DOI
10.1039/c4cc04427d