A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene
Journal Publication ResearchOnline@JCUDeacon, G.B.;Jaroschik, F.;Junk, P.C.;Kelly, R.P.
Abstract
The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.
Journal
Chemical Communications
Publication Name
N/A
Volume
50
ISBN/ISSN
1364-548X
Edition
N/A
Issue
73
Pages Count
3
Location
N/A
Publisher
Royal Society of Chemistry
Publisher Url
N/A
Publisher Location
N/A
Publish Date
N/A
Url
N/A
Date
N/A
EISSN
N/A
DOI
10.1039/c4cc04427d