Rare earth thiocyanate complexes with 18-crown-6 co-ligands

Journal Publication ResearchOnline@JCU
Bakker, Jacinta M.;Deacon, Glen B.;Junk, Peter C.
Peter Junk
Abstract

Reaction of [Ln(NCS)(3)(THF)(4)](2) or [Yb(NCS)(3)(THF)(4)] with 18-crown-6 yields the moisture-stable [Ln(NCS)(3)(18-crown-6)] (Ln = La, Nd, Dy, Yb) complexes. Although the Ln contraction does not affect the coordination number, the crown ether is decreasingly folded with decreasing ion size.

Journal

Polyhedron

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N/A

Volume

52

ISBN/ISSN

1873-3719

Edition

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Issue

Special Issue

Pages Count

5

Location

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Publisher

Elsevier

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Publisher Location

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Publish Date

N/A

Url

N/A

Date

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EISSN

N/A

DOI

10.1016/j.poly.2012.08.028