Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy

Journal Publication ResearchOnline@JCU
Andrews, Philip C.;Gee, William J.;Junk, Peter C.;Krautscheid, Harald;MacLellan, Jonathan G.
Peter Junk
Abstract

Construction of a 3-D supramolecular network from [Ln(cpb)3(H2O)2] (Ln = Nd, Tb; Hcpb = 1-(4-cyanophenyl)-1,3-butanedione) by sequential displacement of a coordinated water by DMF, dimerisation by reciprocal hydrogen bonding in solution and π–π stacking and interdigitation of nitriles has been monitored by in situ fourier transform infrared spectroscopy.

Journal

Chemical Communications

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Volume

46

ISBN/ISSN

1364-548X

Edition

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Issue

32

Pages Count

3

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Publisher

Royal Society of Chemistry

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EISSN

N/A

DOI

10.1039/c0cc00949k