Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II)compounds?

Journal Publication ResearchOnline@JCU
Wiecko, Michal;Deacon, Glen B.;Junk, Peter C.
Peter Junk
Abstract

New EuII and YbII complexes [Ln(Ph2pz)I(thf)4] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh2pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated YbII/YbIII complex [{Yb(dme)4}{YbPh4(dme)}2] has been isolated.

Journal

Chemical Communications

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Volume

46

ISBN/ISSN

1364-548X

Edition

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Issue

28

Pages Count

3

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Publisher

Royal Society of Chemistry

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EISSN

N/A

DOI

10.1039/c0cc01317j