Correlated substituent rotation in the 1,2-benzenedisulfonate anion: the structure of the hydrated potassium salt
Journal Publication ResearchOnline@JCUDeacon, Glen B.;Harika, Rita;Junk, Peter C.;Skelton, Brian W.;White, Allan H.
Abstract
Structure determinations have previously been recorded on the dipotassium and potassium tetramethylammonium salts of 1,2-benzenedisulfonic acid (methanol solvate and hydrate, respectively), as a platform for examining the gear-like interactions of adjacent sulfonate substituents on the aromatic ring. The present report records a single crystal X-ray study of the hydrated potassium salt, showing it to be 8K2[(O3S)2C6H4] · 11H2O, with eight independent anions in the asymmetric unit, enabling a more broadly-based consideration of substituent dispositions.
Journal
Journal of Coordination Chemistry
Publication Name
N/A
Volume
62
ISBN/ISSN
1029-0389
Edition
N/A
Issue
19
Pages Count
12
Location
N/A
Publisher
Taylor & Francis
Publisher Url
N/A
Publisher Location
N/A
Publish Date
N/A
Url
N/A
Date
N/A
EISSN
N/A
DOI
10.1080/00958970903033294