Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster

Journal Publication ResearchOnline@JCU
Gee, William J.;MacLellan, Jonathan G.;Forsyth, Craig M.;Moubaraki, Boujemaa;Murray, Keith S.;Andrews, Philip C.;Junk, Peter C.
Peter Junk
Abstract

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.

Journal

Inorganic Chemistry

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Volume

51

ISBN/ISSN

1520-510X

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Issue

16

Pages Count

3

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Publisher

American Chemical Society

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Date

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EISSN

N/A

DOI

10.1021/ic301382r