The molecular structure of [AlCl(C₅H₃MeNSiMe₃)₂], (C₅H₃MeNHSiMe₃ = 6-methyl-2-(trimethylsilylamino)pyridine)

Journal Publication ResearchOnline@JCU
Jones, Cameron;Junk, Peter C.;Leary, Stuart G.;Smithies, Neil A.
Peter Junk
Abstract

[Extract] the five-coordinate aluminium centre is distorted trigonal bipyramidal with the two aromatic nitrogens in axial positions and the two amido nitrogens and chloride atoms in the equatorial positions. The overall structure is similar to the related [AlCI(8-amidoquinoline)₂], [1] exept that in the present compound, the chelating ligand has a much smaller bite angle, forming a four-menmbered chelate ring rather than a five-membered ring.

Journal

N/A

Publication Name

N/A

Volume

24

ISBN/ISSN

0792-1241

Edition

N/A

Issue

6

Pages Count

2

Location

N/A

Publisher

Walter de Gruyter

Publisher Url

N/A

Publisher Location

N/A

Publish Date

N/A

Url

N/A

Date

N/A

EISSN

N/A

DOI

10.1515/MGMC.2001.24.6.383