Synthesis, structure and optical characteristics of pyridyl substituted diketonates of lanthanoids
Journal Publication ResearchOnline@JCUBrück, Stefan;Hilder, Matthias;Junk, Peter C.;Kynast, Ulrich H.
Abstract
Lanthanoid complexes of a dipyridylsubstituted β-diketonate ligand have been prepared and their structure and optical characteristics have been explored. The structure of these complexes are ten-coordinate centrosymmetric dimers with quadruply bridging diketonate ligands, terminal diketonate ligands and ‘dangling' and bound pyridyl nitrogen atoms. The europium complex diplays strongly luminescent properties while the terbium analogue is completely quenched.
Journal
Inorganic Chemistry Communications
Publication Name
Inorganic Chemistry Communications
Volume
3
ISBN/ISSN
1879-0259
Edition
N/A
Issue
11
Pages Count
5
Location
N/A
Publisher
Elsevier
Publisher Url
N/A
Publisher Location
N/A
Publish Date
N/A
Url
N/A
Date
N/A
EISSN
N/A
DOI
10.1016/S1387-7003(00)00164-7